They are two rough question and I would love to have them answered. Document Preview: The data corresponding to the first-order decomposition of a substance A at 250 K are given on page 4 of the exam. However, there are some problems with the information. Specifically, someone tinkered with the experimental apparatus, raising the temperature to 273 K at a certain time, and later raising it again to another, unspecified temperature. Your job is to complete the following: Determine the times where the temperature was raised to 273 K and the unspecified temperature. Determine the specific reaction rate coefficient for the decomposition at 273 K Determine the activation energy for the reaction. Determine the unspecified final temperature that the experimental system was set to. Assuming this is a unimolecular reaction, use the Arrhenius equation information given above (and some surprisingly direct equations in your text) to determine H­, S ­ and G­ for the transition state species at the final, unspecified temperature (that you should know by now). Time (min) [A] (mmol L-1) 0 10 4.21053 9.66877 8.42105 9.34851 12.63158 9.03885 16.84211 8.73946 21.05263 8.44998 25.26316 8.17009 29.47368 7.89947 33.68421 7.63781 37.89474 7.38482 42.10526 7.14022 46.31579 6.90371 50.52632 6.67504 54.73684 6.45394 58.94737 6.24016 63.15789 6.03347 67.36842 5.83362 71.57895 5.64039 75.78947 5.45356 80 5.27292 84 4.99374 88 4.72933 92 4.47893 96 4.24179 100 4.0172 104 3.8045 108 3.60306 112 3.41229 116 3.23162 120 3.06052 124 2.714 128 2.40672 132 2.13423 136 1.89259 140 1.67831 144 1.48829 148 1.31978 152 1.17035 156 1.03784 160 0.92034 164 0.81614 168 0.72373 172 0.64179 176 0.56913 180 0.50469 184 0.44755 188 0.39687 192 0.35194 196 0.31209 200 0.27676 Determine the molarity of Sr2+ in a saturated aqueous solution of calcium phosphate (Sr3(PO4)2, Ksp = 1.0 ? 10-31) at 298 K. First, assume that the activity coefficient of all species in solution = 1. Using Attachments: homework-p-ch.docx